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Make up two separate solutions. One of Sodium Di-Hydrogen Orthophosphate (NaH2PO4) and one of Di-Sodium Hydrogen Phosphate (Na2HPO4). Make up each to a concentration of 0.2M.

For 0.2M NaH2PO4:
Check the molecular weight of the “kind” of NaH2PO4 you are using.
For NaH2PO4H2O: Mol. Weight = 137.99.
∴ 0.2M = 27.598g/L

For 0.2M Na2HPO4:
Check the molecular weight of the “kind” of Na2HPO4 you are using.
For anhydrous Na2HPO4: Mol. Weight = 141.96.
∴ 0.2M = 28.392g/L

Mix each solution in the following proportions to achieve the desired pH:

NaH2PO4 Na2HPO4 pH
.975 .025 5.3
.950 .050 5.6
.900 .100 5.91
.800 .200 6.24
.700 .300 6.47
.600 .400 6.64
.500 .500 6.81
.400 .600 6.98
.300 .700 7.17
.200 .800 7.38
.100 .900 7.73
.050 .950 8.04

Thanks to Vickey, who gave me this method. Where she got it from I have no idea.

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